Material Safety Data Sheet
Issue date: July 2004
Hazardous
according to criteria of Worksafe Australia
Copper Fluoborate
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1. CHEMICAL
PRODUCT AND COMPANY IDENTIFICATION |
COMPANY DETAILS:
Kendon Chemical & MNFG. Co. Pty Ltd
71 McClure Street
Thornbury, Vic, 3071
Phone: 03 9497 2822
Fax: 03 9499 7225
Product Name: COPPER FLUOBORATE
Synonyms: Copper Tetrafluoborate
Manufacturer's Product Code(s): [to be filled in]
Use:As an electrolyte for metal plating
UN Number: 3289
Proper Shipping Name: TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. (COPPER
FLUOROBORATE 43%, FLUOROBORIC ACID 5%)
Dangerous Goods Class: 6.1
Subsidiary risk: 8
Packing Group: II
Hazchem Code: 2X
NOTE: The product potentially
contains residual amounts of free HF.
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2. COMPOSITION /
INFORMATION ON INGREDIENTS |
SUBSTANCE
NAME Proportion CAS Number
Copper
Fluoroborate 43.3% 38465-60-0
Fluoroboric
Acid (HBF4) 3.8
- 5.2% 16872-11-0
Boric Acid 1.3% 10043-35-3
Hydrofluoric
Acid (released from HBF4 in solution) >0.5% 7664-39-3
Water Balance 7732-18-5
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3.
HAZARD IDENTIFICATION |
Hazardous according to the
criteria of Worksafe Australia
Hazard Category: TOXIC,
CORROSIVE
ACUTE HEALTH EFFECTS
Swallowed:
Toxic if swallowed.
May cause irritation to mouth, throat and stomach with effects including
mucous build up, irritation to the tongue and lips and pains in the stomach.
Eye:
Will cause burns to the eyes with effects including: Pain, tearing,
conjunctivitis and if duration of exposure is long enough, blindness will
occur.
Skin:
Will cause burns to the skin, with effects including; Redness, itchiness,
and possible dermatitis.
Inhaled:
Will cause severe irritation to the nose, throat and respiratory system
with effects including: coughing wheezing, laryngitis, shortness of breath.
Inhalation may result in spasm, inflammation and edema of the larynx and
brochi, chemical pneumonitis and pulmonary edema. Extremely destructive to
tissue of the mucous membranes and upper respiratory tract.
Chronic:
Prolonged or repeated exposure may lead to irreversible damage to health.
Prolonged exposure to fluoride dusts, vapours or mists results in perforation
of the nasal septum. Chronic effects include excessive calcium precipitation by
the fluoride ion in the bones, ligaments and tendons. Prolonged or repeated
skin contact will lead to necrosis (death) of the skin.
Boric acid has been classified as a CATEGORY 3 TOXIC TO REPRODUCTION
(WORKSAFE).
Substances suspected of impairing fertility and or possibly causing birth
defects. Are those substances which have possible developmental toxicity
effects on humans but in respect of which the available information is not
adequate for making a satisfactory assessment. There is some evidence from
appropriate animal or epidemiological studies, but this is insufficient to
place the substance in Category 2.
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4.
FIRST AID MEASURES |
Swallowed:
If swallowed, DO NOT induce vomiting. Seek urgent medical assistance.
Eye:
If material is splashed into eyes, flush with plenty of water for at
least 15 minutes, ensuring eye lids are held open. Immediately transport to
hospital or doctor.
Skin:
If material is splashed onto the skin, remove any contaminated clothing
and wash skin thoroughly with water and soap if available.
Urgently transport to hospital or doctor.
Inhaled:
Remove victim to fresh air. Apply resuscitation if victim is not
breathing - DO NOT USE DIRECT MOUTH - TO - MOUTH METHOD if victim ingested or
inhaled substance; use alternative respiratory method or proper respiratory
device - Administer oxygen if breathing is difficult.
First Aid Facilities:
Eye wash fountain, safety shower and normal wash room facilities.
Advice to Doctor:
Treat symptomatically. Symptoms of fluoride overexposure may include
salivation, nausea, vomiting, abdominal pain, fever, laboured breathing.
Fluoride ion can reduce serum calcium levels possibly causing fatal
hypocalcemia. Prolonged exposure to fluoride dusts, vapours or mists results in
perforation of the nasal septum. Chronic effects include excessive calcium
precipitation by the fluoride ion in the bones, ligaments and tendons.
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5.
FIRE-FIGHTING MEASURES |
Fire/Explosion Hazard
EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide, foam or
water spray.
SPECIAL FIRE FIGHTING
PROCEDURES: Self-contained breathing
apparatus (SCBA) required for fire-fighting personnel.
Flammability
Material does not burn. Containers may explode when heated. Runoff may
pollute waterways.
Fire will produce irritating, toxic and / or corrosive gases.
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6.
ACCIDENTAL RELEASE MEASURES |
EMERGENCY ACTION:
Keep unnecessary people away; Isolate hazard area and
deny entry. Stay upwind; Keep out of low areas. Isolate for 100 m in all
directions if tank, rail car or tanker truck is involved in fire.
SPILL OR LEAK PROCEDURE:
No flares, smoking or flames in hazard area. Stop leak
if you can do it without risk.
Stop leak if you can do it without risk.
SMALL SPILLS:
Neutralize with lime, soda ash or crushed limestone.
Take up with sand, dirt or vermiculite. Place into labelled drum(s) for later disposal.
LARGE SPILLS:
Notify Emergency Services (Police or Fire Brigade). Tell them location,
nature and any information that would be helpful. Contain spill. Safely stop
flow of spill. Bund area. Trainned personnel should wear Personal Protective
equipment as highlighted in this MSDS. Consult an expert regarding disposal of
this product.
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7.
HANDLING AND STORAGE |
Store in a cool place and out of direct sunlight. Store away from sources of heat or flames,
strong alkalis, acids and oxidizing agents. Store in original packages as
approved by manufacturer. Check all fittings, valves, reticulation (piping) and
any ancillary equipment for leaks. A supplied air respirator or a
Self-Contained Breathing Apparatus (SCBA) for emergencies should be available
and checked regularly. For further information please refer to the Engineering
Controls of this MSDS.
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8.
EXPOSURE CONTROLS / PERSONAL PROTECTION |
Exposure Standards
***************************
COPPER FLUOROBORATE
(Worsafe Australia)
[TWA] 1 mg/m³ (Inorganic compounds as Cu )
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FLUOROBORIC ACID
(Worksafe Australia)
[TWA] 2.5 mg/m³ (as
Fluoride)
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BORIC ACID
(Worsafe Australia)
[TWA] 5 mg/m³
Engineering Controls
Toxic and corrosive liquid. Single significant exposure
may cause death. Maintain adequate ventilation at all times. At high
temperatures the solution releases a hazardous mist. Prevent accumulation of
vapours or mists in hollows or sumps.
Mechanical ventilation (dilution and local exhaust), and
control of process conditions. Corrosion resistant materials may be needed
where dust, mists and fumes may be formed. It may be necessary to consider
process or personnel enclosure (fully
enclosed systems).
If engineering controls and work practices are not
effective in preventing or controlling exposure, then suitable personal
protective equipment, which is known to perform satisfactorily, should be used.
Personal Protection Equipment
CLOTHING: PVC, Nitrile, Neoprene, Natural rubber or any
other type of apron or splash suit as recommended by the manufacturer.
GLOVES: PVC, Nitrile, Neoprene, Natural rubber or any
other type of glove as recommended by the manufacturer.
EYES: Chemical goggles or faceshield to protect eyes.
RESPIRATORY PROTECTION: Avoid breathing of vapours or
mists. Select and use respirators in accordance with AS/NZS 1715/1716. When
vapours or mists exceed the exposure standards then the use of an
atmosphere-supplied, positive pressure demand self-contained or airline
breathing apparatus supplied air respirator complying with the requirements of
AS/NZS 1715 is recommended. Filter
capacity and respirator type depends on exposure levels.
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9.
PHYSICAL AND CHEMICAL PROPERTIES |
Appearance: Clear,
blue solution with essentially no odour.
Boiling Point
/ Melting Point: Not
Available
Vapour
Pressure: Not
Available
Specific
Gravity: 1.55
approx.
Flash Point: Not
Applicable
Flammability
Limits: Not
Applicable
pH: 2
approx.
Molecular
Formula: Cu(BF4)2
(Copper Fluoroborate ingredient)
Molecular
Weight: 237.0
(Copper Fluoroborate
ingredient)
Solubility in Water: Complete,
the product is an Aqueous Solution.
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10.
STABILITY AND REACTIVITY |
STABILITY:
Stable under normal conditions of use. In dilute
solution, some hydrolysis to hydrofluoric acid may occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
At high temperatures the solution releases a hazardous
mist of the ingredients. Emits acrid smoke and fumes when heated to
decomposition and may release tin oxides, borates, copper fluoride, boron
trifluoride (speculative), fluoride compounds, and may form hydrogen fluoride
in contact with strong acids.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
Copper Fluoborate is acidic and will react with acid
incompatible materials, eg bases, sulfides, cyanides. It may react vigourosly
with strong oxidizing agents. Corrosive to aluminium.
CONDITIONS TO AVOID:
Heat, flames and incompatibles.
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11.
TOXICOLOGICAL INFORMATION |
Product:
Acute Oral Toxicity (rat): 20-50 mg/kg (Liquid, Packing Group II toxicity
range & Hazardous Substances Toxic Range)
Chronic Effects: Target organs - liver, kidney, lungs, eyes, skin, bones.
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12.
ECOLOGICAL INFORMATION |
This substance may cause adverse effects in the
environment Avoid contaminating
waterways.
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13.
DISPOSAL CONSIDERATIONS |
Whatever cannot be saved for recovery or recycling should be handled as
hazardous waste by an approved waste agency. Processing, use or contamination
of this product may change the waste management options. The waste should be
neutralised with lime in order to immobilise the fluoride as
Calcium Fluoride.
Dispose of container and unused contents in accordance with federal,
state and local requirements.
Advise toxic, corrosive nature. Must be chemically treated to an inert
material prior to disposal in landfill.
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14.
TRANSPORT INFORMATION |
UN Number: 3289
Proper Shipping Name: TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. (COPPER FLUOROBORATE 43%, FLUOROBORIC ACID
5%)
Dangerous Goods Class: 6.1
Subsidiary risk: 8
Packing Group: II
Hazchem Code: 2X
Emergency information(Transport):
Dangerous Goods - Initial Emergency Response Guide (SAA/SNZ HB76:1997)
For TOXIC AND/OR CORROSIVE SUBSTANCES - Guide No: 37
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15.
REGULATORY INFORMATION |
Workplace Hazardous Substance
HAZARD CATEGORY: TOXIC,
CORROSIVE
RISK PHRASES
R25 Toxic if swallowed.
R34 Causes burns.
SAFETY PHRASES
S1/2 Keep locked up and out of
reach of children.
S53 Avoid exposure - obtain
special instructions before use.
S36/37/39 Wear suitable
protective clothing, gloves and eye/face protection.
S26 In case of contact with eyes,
rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin wash immediately with plenty of water and
apply calcium gluconate gel to the affected area.
S27 Take off immediately all
contaminated clothing.
S45 In case of accident or if you
feel unwell, seek medical advice immediately (show the label whenever
possible).
Poison Schedule: S6
Scheduled due to >0.5% HF
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16.
OTHER INFORMATION |
Contact Point
Technical Department After
Hours
03 9497 2822 mobile:
0418-530-461
Disclaimer
The information herein is to the best of our knowledge,
correct and complete. It descibes the safety requirements for this product and
should not be construed as guaranteeing specific properties. Since methods and
conditions are beyond our control we do not accept liability for any damages
resulting from the use of, or reliance on, this information in inappropriate
contexts.
Reviewers Initials / Yr / Mth: JS0006